Publication:
Obtaining the ratio of termination rate constants of poly (methyl methacrylate) by the ultrasonic scission method

dc.contributor.authorÖncül Ayşegül KOÇ
dc.contributor.authorAhmet GİZ
dc.contributor.authorÇatalgil Huceste GİZ
dc.contributor.institutionBAHÇEŞEHİR ÜNİVERSİTESİ
dc.contributor.institutionTanımlanmamış Kurum
dc.contributor.institutionTanımlanmamış Kurum
dc.date.accessioned2025-09-20T20:04:33Z
dc.date.issued2004
dc.date.submitted29.07.2022
dc.description.abstractThe termination step in radical polymerization occurs either by combination or by disproportionation. The termination mechanism of poly (methyl methacrylate) in sonochemical environment is studied by the ultrasonic scission method. The method is improved to give quantitative results by incorporating non-linear least squares analysis of the data. The Chi square map obtained by fitting the data to Schmid's equation gives the ratio of the rate constants for termination by disproportionation and by combination as $k_{td}/k_{tc}$ = 2.6 &plusmn, 0.4.
dc.identifier.endpage11
dc.identifier.issn1434-5641
dc.identifier.issue2
dc.identifier.startpage6
dc.identifier.urihttps://hdl.handle.net/20.500.14719/6040
dc.identifier.volume54
dc.language.isoen
dc.relation.journalARI The Bulletin of the Istanbul Technical University
dc.subjectKimya
dc.subjectUygulamalı
dc.subjectPolimer Bilimi
dc.titleObtaining the ratio of termination rate constants of poly (methyl methacrylate) by the ultrasonic scission method
dc.typeOther
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